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NH2-UiO-66，CAS：1260119-00-3

NH2-UiO-66，CAS:1260119-00-3

NH2-Uio-66

NH2-UiO-66⾦属有机⾻架材料 CAS:1260119-00-3

材料名称：NH2-UIO-66(Zr)

CAS：1260119-00-3

蓄电池模拟器单位分⼦式 C48H5N6O32Zr6抓鸡工具

单位分⼦量 1724.92

包装：⼩包装

储藏⽅法：冷藏

电视机模具是否进⼝：否

质量指标： ≥ 99%

溶解条件：有机溶剂/⽔

产品规格：mg

纯度：99%

货期：现货

⽐表⾯ BET⽐表⾯约650-800 m2/g ; 经调节剂调节后BET可提⾼⾄1200-1500 m2/g

产品形貌黄⾊/淡黄⾊粉末

Pale Yellow Powder

黑刚玉磨料粒径 300-600nm

稳定性

1. NH2-UIO-66 ⾮常稳定，在⽔溶液和酸性条件下稳定。

2）⾼热稳定性、热分解温度⼤于400℃

保存和活化⽅法

2. 常温或低温条件下，⼲燥密封保存

n22003. 建议使⽤前150度（真空）烘箱活化3⼩时

注意事项：

智能鞋柜此产品易受潮，务必常温⼲燥避光保存，使⽤前真空⼲燥处理可使产品性能优化。密封状态下保质期⼀年

英⽂介绍：

MOFs-based photocatalysts always suffer from poor performance owing to its slow charge transfer. Herein, transient metal Cu (CuI/II) species were introduced to NH2-UiO-66(Zr) (Cu-NU0) via in-situ partial reduction of CuII ions to CuI.

A ligand to linker metal charge transfer (LLMCT) pathway in MOFs was constructed for accelerating the

photogenerated electrons transfer from organic linkers to Cu species, greatly enhanced increasing both the carrier density value and the separation efficiency of photogenerated carriers. A longer photogenerated charge lifetime (78.2 ps) was obtained and about 4 times higher than that of Cu-NU0. More photogenerated electrons in the Cu coordinated MOFs (Cu-NU7) were transferred to the outside surface of the MOFs, producing O2− for the photocatalytic oxidation of low-concentration (550 ppb) of NO indoor flow gas. An 88 % removal rate of NO under visible-light irradiation (λ > 420 nm) was obtained and well maintained up to 24 h with excellent durability.CuI/CuII enhanced NH2-UiO-66 (Zr) photocatalysts were developed for effectively oxidizing NO indoor gas (500 ppb) under visible-light irradiation through the ligand to linker metal charge transfer (LLMCT) pathway.

以上资料来⾃⼩编zhn2021.08.25

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